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Graphitic Corrosion



Specimen: 8.25-in. ID cast iron water pipe

Material: Ferritic-pearlitic Gray Cast Iron

Environment: Buried in soil

Background: The 8.25-in. ID water pipe was part of a riser serving a sprinkler system. The pipe, which was buried underground, had fractured into two sections.

Service Life: The cast iron piping had been in service for approximately 30 years.

Findings: Examination of a longitudinal cross-section cut through the pipe wall (shown above) revealed several regions of severe localized corrosion in which the iron constituent of the cast iron had dissolved away leaving only a layer of brittle and weak graphite. This type of cast iron deterioration is known as graphitic corrosion. A metallographic examination of a cross-section transverse to the fracture surface revealed the presence of a wall thickness composed entirely of graphite. The remaining graphite is extremely brittle and weak. Thus, slight loading imposed upon the pipe could result in the fracture of the pipe.

Longitudinal cross-section through the wall of a cast iron pipe, exhibiting severe graphitic corrosion, i.e. dissolution of the iron from the cast iron pipe leaving behind layers of intact graphite.